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Deodorization project of Meixian County sewage treatment plant in Baoji City, Shaanxi Province
Sewage deodorization project of petrochemical industrial park in Karamay, Xinjiang
Wastewater Deodorization Project in Jingubei District, Sha County, Sanming City, Fujian Province
Wastewater Deodorization Project of the Second Urban Sewage Treatment Plant Project in Qidong City, Nantong City, Jiangsu Province
Deodorization project in Jilin Chemical Industry Park, Jilin Province
Wastewater Deodorization Project of Pingshan Industrial Park in Shicheng County, Ganzhou City, Jiangxi Province
Procurement of Deodorization Equipment for the Biannan Sewage Treatment Plant Project in Suma Park, Suzhou City, Anhui Province
Deodorization project of Xiaosong Entrepreneurship Park sewage treatment plant in Shicheng County, Ganzhou City, Jiangxi Province
Shandong Province Weifang Qingzhou Qianshan Sewage Treatment Plant Upgrading and Renovation Project
Deodorization Project of Pengyao Municipal Wastewater Treatment Plant in Xian County, Cangzhou City, Hebei Province
EPC Project for Wastewater Deodorization of Huangxing Haijixing Phase II Wastewater Treatment Center in Changsha City, Hunan Province
Jianghai Phase II Deodorization Project in Qidong City, Nantong City, Jiangsu Province
Supply Project of Complete Equipment for Washing Tower of Heping Road Pump Station in Qidong City, Nantong City, Jiangsu Province
Procurement Project of Deodorization Equipment for Jianghai Sewage Treatment Co., Ltd. in Qidong City, Nantong City, Jiangsu Province
Deodorization treatment project for sewage pump room at Yuen Long Jinxiu Huawei Bus Station in Hong Kong
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Deodorization of chemical wastewater
Fine chemical wastewater exhaust gas treatment solutions
Home Solution Wastewater Deodorization Deodorization of chemical wastewater Fine chemical wastewater exhaust gas treatment
  • Industry Overview
  • Sources of Exhaust Gases
  • Exhaust Gas Composition
  • Emission Standards
  • Treatment Challenges
  • Processes
  • Eclear Advantages
  • Related Cases
  • Related Equipment
INDUSTRY OVERVIEW
Fine chemical wastewater exhaust gas treatment

Fine chemical production process is different from the general chemical production, its production process, not only including chemical synthesis (or from natural substances in the separation, extraction), but also includes the agent processing and commercialisation, composed of two parts. The chemical synthesis process, mostly from the basic chemical raw materials, made of intermediates, and then made into medicine, dyes, pesticides, organic pigments, surfactants, spices and other fine chemicals.

SOURCES OF EXHAUST GASES
Solvent extraction
Adsorption
Organisms
Membrane separation
Oxidisation
Incinerators
EXHAUST GAS COMPOSITION
H₂S
NH₃
Dimethyl disulfide
Sulphur-containing compounds
Diamine
Trimethylamine
Methyl mercaptan
Methyl sulphide
Thiols
Styrene
Acetaldehyde
Propionaldehyde
Butyraldehyde
Aromatic hydrocarbons
Aromatic compounds
Amines
Hydrocarbons
Lipids
Phenols
Alcohols
Aldehydes
Ketones
Volatile Organic Compounds VOCs
Sulphur ethers
Phthalamines
Methyl mercaptan
Dimethyl sulphide
Dimethyl disulfide
Methyl ammonia
Dimethyl ammonia
The wastewater treatment system in the fine chemical industry not only emits ammonia, hydrogen sulphide and sulphur compounds, which are common in the wastewater treatment process, but also emits a large number of volatile organic compounds (VOCs), with the main points of generation including the pre-treatment stage, the biochemical treatment stage, the in-depth treatment stage, and the upgrading of the pumping station and the sludge treatment system.
EMISSION STANDARDS
Number
Control project
Exhaust pipe height(m)
Draft for soliciting opinions allows for emission rates (kg/h)
Emission release rate of version 93(kg/h)
Check location
1
NH3
15
0.6
4.9
Workshop or production facility exhaust pipe
2
C3H9N
15
0.15
0.54
3
H2S
15
0.06
0.33
4
CH3SH
15
0.006
0.04
5
(CH3)2S
15
0.06
0.33
6
C2H6S2
15
0.15
0.43
7
CS2
15
1.5
1.5
8
C8H8
15
3.0
6.5
9
Odor concentration
Exhaust pipe height (m) ≥ 15
Standard value (dimensionless) 1000
Standard value (dimensionless) 2000
TREATMENT CHALLENGES
Complex odour components
The fine chemical industry has a wide range of raw materials, resulting in a wide range of exhaust gases.
More sources of odour gas pollution
Taking the fine chemical wastewater treatment station as an example, it is mainly generated in the sewage pumping station, inlet grill, aeration and sedimentation tank, sludge treatment facility and sludge treatment process.
High concentration of exhaust gases
Fine chemical industry mostly use organic raw materials, resulting in more organic components in the sewage, volatile organic odour pollutants concentration is large. Some organic pollutants also have a certain degree of toxicity.
High variability of odour gas generation
The odour produced by each unit of the fine chemical industry also varies with water quantity, water quality, climatic conditions, operating parameters and other factors.
PROCESS FLOW
ECLEAR ADVANTAGES
Strength guarantee
More than 20 waste gas treatment technologies developed by the Sino British joint venture team of a national high-tech enterprise
Quality assurance
200+ project cases of stable operation without worrying about advantages
After-sales service
Free 24-hour online service with after-sales team
Technical Team
Team members have more than ten years of experience in waste gas management, including three registered HVAC engineers registered drainage engineers, two builders
Sourcing company
Cost-effective equipment engineering for better control of your costs
Environmental compliance
Full process management services make it easy for you to cope with the environmental protection bureau acceptance of meeting the new exhaust emission standards
Eclear Environmental RELATED EQUIPMENT
Zeolite wheel+CO
The zeolite rotary device+catalytic combustion of CO is mainly suitable for treating high concentration CO waste gas. Usually, when the CO concentration is 500 ppm (volume fraction) or higher, a zeolite rotary device combined with catalytic combustion of CO is required for treatment. If the CO concentration is low, other waste gas treatment technologies may be more suitable. Zeolite rotary device is a technology used to separate components from gas mixtures. This type of device usually includes many zeolite molecular sieve wheels, which can selectively adsorb certain molecules without adsorbing other molecules, thereby achieving component separation in gas mixtures. Catalytic combustion of CO is a technology that converts CO (a toxic and harmful gas) into CO2 (a relatively harmless gas). This technology uses catalysts to accelerate the reaction between CO and oxygen, thereby reducing the concentration of CO.
Zeolite wheel+TO
Zeolite wheel+TO direct combustion furnace is an efficient and environmentally friendly industrial waste gas treatment equipment. It can effectively treat various organic pollutants in industrial waste gas through two methods: physical adsorption and high-temperature incineration. This device has the advantages of high efficiency, energy conservation, wide applicability, and easy maintenance, and has broad application prospects in the field of industrial waste gas treatment in the future.
Zeolite wheel+RCO
The zeolite wheel+RCO catalytic combustion equipment is currently a mature and practical process in the field of organic waste gas treatment in China. Adopting a three step continuous program of adsorption desorption cooling, with simultaneous adsorption and desorption. The zeolite wheel first adsorbs and collects organic waste gas, compresses it, and increases its concentration. Then, high concentration waste gas molecules are desorbed from the zeolite wheel and sent to a catalytic oxidation furnace (CO furnace) for flameless combustion. To achieve the purpose of purifying organic waste gas. The zeolite wheel+RCO equipment mainly consists of exhaust gas pretreatment system, zeolite wheel adsorption concentration system, desorption system, catalytic combustion system, cooling and drying system, and automatic control system.
Zeolite wheel+RTO
The zeolite wheel+RTO process is currently one of the hottest processes in the waste gas treatment industry. Compared to other new materials, industries such as new energy, chemical, and semiconductor directly use RTO for incineration. The zeolite wheel RTO process has very guaranteed compliance and safety performance. The working principle of zeolite rotary RTO is to use combustion reactions at high temperatures to oxidize organic compounds in exhaust gas into harmless carbon dioxide and water, thereby achieving the goal of purifying exhaust gas. Its core is a rotating heat exchanger filled with adsorption materials such as zeolite.
Spray tower
Spray tower, as a type of environmental waste gas treatment equipment, exists. According to its working principle, it can be divided into circulating water spray tower, alkali spray tower, and acid spray tower (also known as acid washing tower). According to the material of the tower, it is divided into fiberglass spray towers, PP spray towers, and stainless steel spray towers. Choose a reasonable spray material and spray process based on the different properties of the exhaust gas. Spray tower is an important industrial waste gas treatment equipment, whose working principle is to use water and power technology to spray liquid or gas in a mist form into the waste gas, in order to remove harmful substances in the waste gas.
Washing tower
Washing tower is a mature waste gas treatment equipment widely used in pre-treatment of industrial waste gas treatment, dust removal, and other aspects. Gas enters the tower and fully contacts, adsorbs, and dissolves with the washing liquid inside the tower, achieving purification effect. The design forms of Yi cleaning towers are diverse, and vertical or horizontal structures can be used according to the project application site. The commonly used materials for washing tower equipment include PP, FRP, and stainless steel. PP and FRP are commonly used in chemical absorption towers and have the characteristics of acid resistance, alkali resistance, and corrosion resistance. Stainless steel materials can be used for high-temperature exhaust gas.
VOCs integrated processing equipment
The activated carbon adsorption box (YQA all-in-one machine) is a VOCs waste gas treatment equipment developed by Eclear Environmental through years of research and engineering experience combined with the photocatalyst technology of university research institutions. It adopts a dual process combination of photocatalytic oxidation and activated carbon adsorption, as well as an integrated design concept.
Biological deodorization
Biological deodorization is the process of using effective deodorizing bacteria and a reasonable equipment structure to oxidize and decompose large molecules or structurally complex organic matter into simple inorganic substances such as water and carbon dioxide through differentiation. Eclear Environmental Biological Deodorization has been improved compared to its peers, adopting an integrated process of pre-treatment and deep adsorption of biological treatment to ensure the stability of the intake during the biological treatment stage. At the same time, deep treatment is not configured at the end, which can ensure that the exhaust gas meets the standard emission when the emission concentration exceeds the design emission concentration.
Biological filter
A biological filter is a device that uses effective deodorizing bacteria and a reasonable equipment structure to oxidize and decompose large molecules or structurally complex organic matter into simple inorganic substances such as water and carbon dioxide through differentiation. Eclear Environmental Biological Filter has been improved compared to its peers, adopting an integrated treatment process of pre-treatment and deep adsorption of biological treatment to ensure the stability of the intake during the biological treatment stage. At the same time, deep treatment is not configured at the end, which can ensure that the exhaust gas meets the standard when the emission concentration exceeds the design.
Coupling catalytic all-in-one machine
The equipment adopts a stainless steel fixed pry mounted fully sealed structure, which is easy to install. The interior is coated with stainless steel special anti-corrosion material, which is resistant to acid, alkali and waste gas environments. The equipment has a long service life and is composed of a pre-treatment section, a coupled reaction device, and an array drawer type module. The high-energy particle field generated by the coupling catalytic network of precious metals is irradiated through the ultraviolet band to the coupling synergy effect of independently prepared precious metals and titanium dioxide nanoparticles. VOCs organic waste gas is decomposed into carbon dioxide, water, etc. Other waste gas molecules that have not been completely degraded can be oxidized into water-soluble small molecules and some active free radicals.
Activated carbon adsorption box
Activated carbon adsorption box is an environmentally friendly mechanical product that filters waste gas and adsorbs odors. This equipment is used to clean organic chemical waste gas and spray waste gas with high concentration. Activated carbon has a high-strength adsorption level. When the waste gas is powered by a centrifugal fan, negative pressure enters the adsorption box and then enters the activated carbon adsorption layer, it has a very good adsorption effect on organic solution waste gas.
Coupling catalytic exhaust gas treatment equipment
The equipment adopts a stainless steel fixed pry mounted fully sealed structure, which is easy to install. The interior is coated with stainless steel special anti-corrosion material, which is resistant to acid, alkali and waste gas environments. The equipment has a long service life and is composed of a pre-treatment section, a coupled reaction device, and an array drawer type module. The high-energy particle field generated by the coupling catalytic network of precious metals is irradiated through the ultraviolet band to the coupling synergy effect of independently prepared precious metals and titanium dioxide nanoparticles. VOCs organic waste gas is decomposed into carbon dioxide, water, etc. Other waste gas molecules that have not been completely degraded can be oxidized into water-soluble small molecules and some active free radicals.
RCO thermal storage catalytic combustion
Regenerative catalytic combustion (RCO) is a method of using catalysts to decompose organic waste gases into harmless small molecules such as carbon dioxide and water. Due to the need to consume heat in the reaction, it is called regenerative catalytic combustion method. The RCO device mainly consists of three parts: a purification chamber, a preheating chamber, and a high-temperature gas outlet, with the temperature of the preheating chamber generally ranging from 300 to 600 ° C; The purification room is equipped with a packing layer to adsorb pollutants from organic waste gas; The high-temperature gas outlet is connected to the atmosphere to recover heat.
RTO thermal storage oxidation furnace
The English name of a regenerative thermal incinerator is "Regenerative Thermal Oxidizer", therefore it is abbreviated as "RTO". The principle is to heat the organic waste gas to above 800 degrees Celsius, causing the VOC in the waste gas to oxidize and decompose into carbon dioxide and water. The high-temperature gas generated by oxidation flows through a specially designed ceramic heat storage body, causing the ceramic body to heat up and "store heat". This "heat storage" is used to preheat the subsequent organic waste gas entering, thereby saving fuel consumption for waste gas heating. The ceramic heat storage body should be divided into three compartments, each of which should go through the procedures of heat storage, heat release, and cleaning in sequence, and work continuously. After the heat storage chamber releases heat, a portion of the treated and qualified clean exhaust should be immediately introduced to clean the chamber (to ensure a VOC removal rate of over 95%). Only after the cleaning is completed can the "heat storage" program be entered.
CO catalytic combustion
Catalytic combustion is a purification method that uses a catalyst to oxidize and decompose combustible substances in exhaust gas at lower temperatures. So, catalytic combustion is also known as catalytic chemical conversion. Due to the catalyst accelerating the process of oxidation and decomposition, most hydrocarbons can be completely oxidized through the catalyst at temperatures ranging from 300 to 450 ℃. Compared with thermal combustion, catalytic combustion requires less auxiliary fuel, consumes less energy, and has a smaller volume of equipment and facilities. However, due to the poisoning of the catalyst used, the replacement of the catalytic bed, and the high cost of cleaning, the promotion and application of this method in industrial production processes have been affected.
TO direct combustion oxidation furnace
Direct combustion incinerators process VOCs through the principle of high-temperature oxidation. The internal structure of conventional furnaces is a cavity structure, and various heat recovery devices such as heat exchangers and boilers can be installed outside the furnace according to customer needs. Direct combustion incinerators can be widely used for complex waste gases with high concentrations and particulate matter, and effectively recover the heat energy released during the oxidation process. Direct combustion incinerators have diverse shapes and can be designed according to the characteristics of the site space, such as square and cylindrical chambers. They can also be made into vertical furnaces, horizontal furnaces, L-shaped furnaces, etc.
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